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It has been more than 5 years since I started using Linux - I've always been on GNOME, making a brief switch to XFCE in between. Although KDE is more eye-candy and better than GNOME in few instances, I never liked to use it much. But these days, there are many KDE applications that you probably cannot live without, if you're using Linux.
Here are few such applications:
1) [w:Amarok|Amarok]
[Amarok is something like (repeat *something like*) ITunes for Linux. But the features it provides with not much complexity is mind blowing (for a Linux user)]
2) [w:Kate (text editor)|Kate].
3) [:http://en.wikipedia.org/wiki/List_of_KDE_applications#Multimedia|KdeTV]
4) [w:KSnapshot|KSnapshot]
5) [w:Konsole|Konsole]
Recently, I switched back to Human theme on Ubuntu from [:http://art.gnome.org/themes/gtk2/468|Industrial] and found out that it is far more optimized now; looks better too. But one feature I'll always miss on GNOME is the analog clock that is available on KDE panel. :)